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基于白藜芦醇与石墨烯相互作用的红酒中白藜芦醇含量的电化学评估

Electrochemical Evaluation of -Resveratrol Levels in Red Wine Based on the Interaction between Resveratrol and Graphene.

作者信息

Liu Lantao, Zhou Yanli, Kang Yiyu, Huang Haihong, Li Congming, Xu Maotian, Ye Baoxian

机构信息

Henan Engineering Laboratory of Green Synthesis for Pharmaceuticals, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000, China.

Henan Key Laboratory of Biomolecular Recognition and Sensing, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000, China.

出版信息

J Anal Methods Chem. 2017;2017:5749025. doi: 10.1155/2017/5749025. Epub 2017 Jul 27.

Abstract

-Resveratrol is often considered as one of the quality standards of red wine, and the development of a sensitive and reliable method for monitoring the -resveratrol levels in red wine is an urgent requirement for the quality control. Here, a novel voltammetric approach was described for probing -resveratrol using a graphene-modified glassy carbon (GC) electrode. The proposed electrode was prepared by one-step electrodeposition of reduced graphene oxide (ERGO) at a GC electrode. Compared with the bare GC electrode, the introduced graphene film on the electrode surface dramatically improved the sensitivity of the sensor response due to the - interaction between the graphene and -resveratrol. The developed sensor exhibited low detection limit of 0.2 M with wide linear range of 0.8-32 M and high stability. For the analysis of -resveratrol in red wine, the high anti-interference ability and the good recoveries indicated the great potential for practical applications.

摘要

白藜芦醇常被视为红酒质量标准之一,开发一种灵敏可靠的方法来监测红酒中白藜芦醇的含量是质量控制的迫切需求。在此,描述了一种使用石墨烯修饰玻碳(GC)电极探测白藜芦醇的新型伏安法。所提出的电极通过在GC电极上一步电沉积还原氧化石墨烯(ERGO)制备。与裸GC电极相比,电极表面引入的石墨烯膜由于石墨烯与白藜芦醇之间的相互作用显著提高了传感器响应的灵敏度。所开发的传感器检测限低至0.2 μM,线性范围宽达0.8 - 32 μM,且稳定性高。对于红酒中白藜芦醇的分析,高抗干扰能力和良好的回收率表明其具有巨大的实际应用潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/486f/5551533/7fc488a111dc/JAMC2017-5749025.sch.001.jpg

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