Nanomaterial Research Lab, Department of Textile Engineering, Mehran University of Engineering and Technology, Jamshoro, 76060, Pakistan; Nano Fusion Technology Research Lab, Division of Frontier Fibers, Institute for Fiber Engineering (IFES), Interdisciplinary Cluster for Cutting Edge Research (ICCER), Shinshu University, Tokida 3-15-1, Ueda, Nagano Prefecture, 386-8567, Japan.
Nanomaterial Research Lab, Department of Textile Engineering, Mehran University of Engineering and Technology, Jamshoro, 76060, Pakistan.
Carbohydr Polym. 2017 Oct 15;174:443-449. doi: 10.1016/j.carbpol.2017.06.125. Epub 2017 Jul 3.
Recent advancement in dyeing of nanofibers has been accelerated to improve their aesthetic properties, however, achieving good color fastness remains a challenge. Therefore, we attempt to improve the color fastness properties nanofibers. Vat dyes are known for better color fastness and their application on nanofibers has not been investigated to date. Herein, we report dyeing of regenerated cellulose nanofibers (RCNF) that were produced from precursor of cellulose acetate (CA) followed by deacetylation process. The resultant RCNF was dyed with two different vat dyes and the color attributes were examined under spectrophotometer which showed outstanding color build-up. Morphological of CA before and after deacetylation and before and after vat dyeing was investigated under TEM, FE-SEM and SEM respectively. The vat dyed RCNF were further characterized by FTIR and WAXD. Excellent color fastness results demonstrate that vat dyed RCNF can potentially be considered for advanced apparel applications.
近年来,纳米纤维的染色技术取得了飞速发展,以改善其美观性能,然而,要达到良好的色牢度仍然是一个挑战。因此,我们试图改善纳米纤维的色牢度性能。还原染料以其更好的色牢度而闻名,但其在纳米纤维上的应用尚未得到研究。在此,我们报告了用醋酸纤维素(CA)的前体经脱乙酰化过程制备的再生纤维素纳米纤维(RCNF)的染色。所得的 RCNF 用两种不同的还原染料进行染色,并在分光光度计下检查颜色属性,结果显示出色的颜色形成。通过 TEM、FE-SEM 和 SEM 分别研究了 CA 在脱乙酰化前后以及还原染料染色前后的形态。用 FTIR 和 WAXD 进一步表征还原染料染色的 RCNF。优异的色牢度结果表明,还原染料染色的 RCNF 可能有潜力用于高级服装应用。