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阳离子纤维素纳米纤维:用于服装应用的阴离子反应性染料的制备和染色性。

Cationic-cellulose nanofibers: preparation and dyeability with anionic reactive dyes for apparel application.

机构信息

Nano Fusion Technology Research Group, Faculty of Textile Science and Technology, Shinshu University, Ueda, Nagano 386-8567, Japan.

出版信息

Carbohydr Polym. 2013 Jan 2;91(1):434-43. doi: 10.1016/j.carbpol.2012.08.046. Epub 2012 Aug 22.

Abstract

Continuous effort in research and development of nanofibers for apparel usage has been focused within their functional properties only. We investigated esthetic properties by producing colored cationic-cellulose nanofibers for the very first time for the potential application of apparel use. The cellulose acetate nanofibers were electrospun followed by deacetylation and cationization to produce functional cationic-cellulose nanofibers and then dyed with anionic reactive dyes. The spectrophotometric measurement of dyed samples was carried out to determine color coordinates and color yield values. The cationic-cellulose nanofibers showed enhanced color yield and dye fixation without addition of an electrolyte in comparison to cellulose nanofibers. The cationization of cellulose nanofibers significantly enhanced the color yield values of around 76% at dye concentrations of 5%. Excellent color fastness results demonstrate that these new colored and breathable materials can potentially be considered as future apparel for casual or fashion.

摘要

在研究和开发用于服装用途的纳米纤维方面,人们一直专注于其功能特性。我们通过首次生产有色阳离子纤维素纳米纤维来研究其美观特性,以期将其应用于服装。醋酸纤维素纳米纤维经过静电纺丝、脱乙酰化和阳离子化,制成功能性阳离子纤维素纳米纤维,然后用阴离子反应性染料染色。对染色样品进行分光光度测量,以确定颜色坐标和颜色产率值。与纤维素纳米纤维相比,阳离子纤维素纳米纤维在不添加电解质的情况下,显示出增强的颜色产率和染料固着率。纤维素纳米纤维的阳离子化显著提高了约 76%的颜色产率值,在 5%的染料浓度下。出色的色牢度结果表明,这些新型彩色透气材料有可能被视为未来的休闲或时尚服装。

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