A Comprehensive Review on Cellulose Nanofibers, Nanomaterials, and Composites: Manufacturing, Properties, and Applications.

Cellulose nanofibers (CNFs), cellulose nanomaterials (CNMs), and cellulose-based composites represent a convergence of material science, sustainability, and advanced engineering, paving the way for innovative and eco-friendly materials. This paper presents a comprehensive review of these materials, encompassing their extraction, preparation methods, properties, applications, and future directions. The manufacturing of CNFs and CNMs leverages diverse techniques-chemical, mechanical, and enzymatic-with each offering distinct advantages in tailoring material characteristics to meet specific needs. Strategies for functionalization and surface modification are detailed, highlighting their role in enhancing the properties of CNFs and composites while addressing challenges in scaling production to industrial levels. The structural, mechanical, thermal, optical, electrical, and biocompatibility properties of CNFs, CNMs, and their composites are explored, underscoring their versatility for applications across various industries. Cellulose-based composites, in particular, demonstrate exceptional tunable properties for specific uses, although achieving uniform dispersion remains a key technical hurdle. These materials have applications in packaging, automotive, aerospace, biomedical devices, energy storage, and environmental remediation. Emerging research trends emphasize the integration of CNFs and CNMs with advanced manufacturing technologies, promoting sustainable practices and life cycle considerations while advancing their commercialization potential. This rapidly evolving field holds immense promise for addressing global challenges by creating high-performance, and sustainable materials. This review is crucial in advancing the understanding of cellulose nanofibers, nanomaterials, and cellulose-based composites, providing valuable insights that will drive the development of sustainable, high-performance materials for a wide range of applications, ultimately addressing key global challenges.