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具有增强储锂性能的核壳结构硅-介孔二氧化钛复合纳米球的逐步组装制备

Step-by-step assembly preparation of core-shell Si-mesoporous TiO composite nanospheres with enhanced lithium-storage properties.

作者信息

Sun Lin, Wang Fei, Su Tingting, Du Hong-Bin

机构信息

State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.

出版信息

Dalton Trans. 2017 Sep 12;46(35):11542-11546. doi: 10.1039/c7dt02132a.

DOI:10.1039/c7dt02132a
PMID:28825065
Abstract

Core-shell structured Si-mesoporous TiO (Si@mTiO) composite nanospheres are designed and prepared via a step-by-step assembly method. Si@mTiO exhibit excellent lithium-storage properties when used as anode materials in lithium ion batteries. The reversible specific capacity is maintained at as high as 700 mA h g with no capacity decay even after 200 cycles at 1 A g.

摘要

通过逐步组装法设计并制备了核壳结构的硅-介孔二氧化钛(Si@mTiO)复合纳米球。当用作锂离子电池的负极材料时,Si@mTiO表现出优异的储锂性能。即使在1 A g的电流密度下循环200次后,可逆比容量仍保持高达700 mA h g,且没有容量衰减。

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