Saini Anoop Kumar, Natarajan Kaushik, Mobin Shaikh M
Discipline of Chemistry, Indian Institute of Technology Indore, Simrol, Khandwa Road, Indore 453552, India.
Chem Commun (Camb). 2017 Aug 31;53(71):9870-9873. doi: 10.1039/c7cc04392a.
We report a rare combination of two unique properties of an azine based ligand (H3L): in a solid-state crystalline material it shows highly flexible and elastic behavior which on triggering with light results in slight deviation with phase transformation at the Single-Crystal-to-Single-Crystal (SCSC) level. Furthermore, in the solution state it acts as a highly selective, sensitive and reversible Al sensor with a detection limit of 42 nM.
我们报道了一种基于吖嗪的配体（H3L）的两种独特性质的罕见组合：在固态晶体材料中，它表现出高度灵活和弹性的行为，在光触发下，在单晶到单晶（SCSC）水平上会发生轻微偏差并伴有相变。此外，在溶液状态下，它作为一种高度选择性、灵敏且可逆的铝传感器，检测限为42 nM。
