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机械响应性柔性晶体

Mechanoresponsive Flexible Crystals.

作者信息

Wang Zhihua, Han Wenqing, Shi Rongchao, Han Xiao, Zheng Yongshen, Xu Jialiang, Bu Xian-He

机构信息

School of Materials Science and Engineering, Smart Sensing Interdisciplinary Science Center, Frontiers Science Center for New Organic Matter, Nankai University, Tongyan Road 38, Tianjin 300350, P. R. China.

Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300350, P. R. China.

出版信息

JACS Au. 2024 Jan 16;4(2):279-300. doi: 10.1021/jacsau.3c00481. eCollection 2024 Feb 26.

DOI:10.1021/jacsau.3c00481
PMID:38425899
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10900217/
Abstract

Flexible crystals have gained significant attention owing to their remarkable pliability, plasticity, and adaptability, making them highly popular in various research and application fields. The main challenges in developing flexible crystals lie in the rational design, preparation, and performance optimization of such crystals. Therefore, a comprehensive understanding of the fundamental origins of crystal flexibility is crucial for establishing evaluation criteria and design principles. This Perspective offers a retrospective analysis of the development of flexible crystals over the past two decades. It summarizes the elastic standards and possible plastic bending mechanisms tailored to diverse flexible crystals and analyzes the assessment of their theoretical basis and applicability. Meanwhile, the compatibility between crystal elasticity and plasticity has been discussed, unveiling the immense prospects of elastic/plastic crystals for applications in biomedicine, flexible electronic devices, and flexible optics. Furthermore, this Perspective presents state-of-the-art experimental avenues and analysis methods for investigating molecular interactions in molecular crystals, which is vital for the future exploration of the mechanisms of crystal flexibility.

摘要

柔性晶体因其卓越的柔韧性、可塑性和适应性而备受关注，使其在各种研究和应用领域广受欢迎。开发柔性晶体的主要挑战在于此类晶体的合理设计、制备及性能优化。因此，全面了解晶体柔韧性的基本起源对于建立评估标准和设计原则至关重要。本综述对过去二十年柔性晶体的发展进行了回顾性分析。它总结了针对不同柔性晶体的弹性标准和可能的塑性弯曲机制，并分析了其理论基础和适用性的评估。同时，还讨论了晶体弹性与塑性之间的兼容性，揭示了弹性/塑性晶体在生物医学、柔性电子器件和柔性光学应用中的巨大前景。此外，本综述介绍了用于研究分子晶体中分子相互作用的最新实验途径和分析方法，这对于未来探索晶体柔韧性机制至关重要。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa13/10900217/72fee372e310/au3c00481_0014.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa13/10900217/77212a03e620/au3c00481_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa13/10900217/47a080f14043/au3c00481_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa13/10900217/f3a39f0dccfb/au3c00481_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa13/10900217/72238d903af7/au3c00481_0009.jpg
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