Tao Chen-Lei, Chen Bin, Liu Xun-Gao, Zhou Li-Jiao, Zhu Xiao-Li, Cao Jun, Gu Zhi-Guo, Zhao Zujin, Shen Liang, Tang Ben Zhong
College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 310036, China.
Chem Commun (Camb). 2017 Sep 5;53(72):9975-9978. doi: 10.1039/c7cc05031c.
A novel pillared-layered entangled luminescent metal-organic framework [Zn(bpdc)(BPyTPE)] (1) (BPyTPE = (E)-1,2-diphenyl-1,2-bis(4-(pyridin-4-yl)phenyl)ethene) has been designed and constructed. The solvent-free 1 exhibits strong blue-green emission with an excellent fluorescence quantum yield of 99% and provides a facile and reversible method to sensitively and quantitatively detect trace pesticide of 2,6-dichloro-4-nitroaniline.
一种新型的柱状层状纠缠发光金属有机框架[Zn(bpdc)(BPyTPE)] (1)（BPyTPE = (E)-1,2-二苯基-1,2-双(4-(吡啶-4-基)苯基)乙烯）已被设计并构建。无溶剂的1表现出强烈的蓝绿色发射，荧光量子产率高达99%，并提供了一种简便且可逆的方法来灵敏且定量地检测痕量农药2,6-二氯-4-硝基苯胺。
