Polymer Science Group, The University of Melbourne, Department of Chemical and Biomolecular Engineering, Melbourne, 3010, Australia.
Sonochemistry Research Team, The University of Melbourne, School of Chemistry, Melbourne, 3010, Australia.
Angew Chem Int Ed Engl. 2017 Sep 25;56(40):12302-12306. doi: 10.1002/anie.201706771. Epub 2017 Sep 1.
The ultrasonic irradiation of aqueous solution is demonstrated to be a suitable source of initiating radicals for a controlled radical polymerization when conducted in the presence of a thiocarbonylthio-containing reversible addition-fragmentation chain transfer (RAFT) agent. This allows for a highly "green" method of externally regulated/controlled polymerization with a potentially broad scope for polymerizable monomers and/or polymer structures.
超声辐射水溶液被证明是一种合适的引发自由基源，当在含有硫羰基硫的可逆加成-断裂链转移（RAFT）试剂存在下进行时，可用于可控自由基聚合。这为具有广泛聚合单体和/或聚合物结构的外部调节/控制聚合提供了一种高度“绿色”的方法。
