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一种长寿命的二茂铁共轭铱(III)配合物,用于在水中和人血清中痕量 DMSO 的灵敏开环荧光检测。

A long-lived ferrocene-conjugated iridium(III) complex for sensitive turn-on luminescence detection of traces of DMSO in water and human serum.

机构信息

Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong, China.

State Key Laboratory of Quality Research in Chinese Medicine, Institute of Chinese Medical Sciences, University of Macau, Macau, China.

出版信息

Anal Chim Acta. 2017 Sep 1;984:193-201. doi: 10.1016/j.aca.2017.06.042. Epub 2017 Jun 30.

DOI:10.1016/j.aca.2017.06.042
PMID:28843564
Abstract

The development of an efficient sensor for the determination of the DMSO content in aqueous solution is highly desirable in a number of chemical industries. Presented herein is a ferrocene-conjugated iridium(III) complex, which exhibits remarkable capability to detect traces of DMSO (<1% v/v) in aqueous solution through a turn-on luminescence sensing mechanism. The extraordinary sensitivity and selectivity of this newly developed complex for DMSO renders it as one of the most powerful DMSO sensors known.

摘要

在许多化学工业中,开发一种用于测定水溶液中 DMSO 含量的高效传感器是非常需要的。本文介绍了一种二茂铁共轭铱(III)配合物,它通过开启式荧光传感机制表现出检测水溶液中痕量 DMSO(<1%v/v)的卓越能力。这种新开发的配合物对 DMSO 的非凡灵敏度和选择性使它成为已知的最强大的 DMSO 传感器之一。

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