A highly crystalline oriented metal-organic framework thin film with an inorganic pillar.

作者信息

Watanabe Yuki, Haraguchi Tomoyuki, Otsubo Kazuya, Sakata Osami, Fujiwara Akihiko, Kitagawa Hiroshi

机构信息

Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto, 606-8502, Japan.

出版信息

Chem Commun (Camb). 2017 Sep 12;53(73):10112-10115. doi: 10.1039/c7cc03828c.

We report a step-by-step route to fabricate the first example of a crystalline oriented metal-organic framework thin film having an anionic inorganic pillar ligand, {Cu(4,4'-bipyridyl)(SiF)}. X-ray study and sorption analysis revealed its high crystallinity and porous character.