氧化石墨烯作为合成前列腺素衍生物中用于非对映选择性转移氢化反应的催化剂。
Graphene oxide as a catalyst for the diastereoselective transfer hydrogenation in the synthesis of prostaglandin derivatives.
作者信息
Coman Simona M, Podolean Iunia, Tudorache Madalina, Cojocaru Bogdan, Parvulescu Vasile I, Puche Marta, Garcia Hermenegildo
机构信息
Department of Organic Chemistry, Biochemistry and Catalysis, Chemistry, University of Bucharest, Bdul Regina Elisabeta 4-12, Bucharest 030016, Romania.
出版信息
Chem Commun (Camb). 2017 Sep 14;53(74):10271-10274. doi: 10.1039/c7cc05105k.
PMID:28862277
Abstract
Modification of GO by organic molecules changes its catalytic activity in the hydrogen transfer from i-propanol to enones, affecting the selectivity to allyl alcohol and diastereoselectivity to the resulting stereoisomers. It is noteworthy the system does not contain metals and is recyclable.
摘要
通过有机分子对氧化石墨烯（GO）进行改性，改变了其在异丙醇向烯酮的氢转移反应中的催化活性，影响了对烯丙醇的选择性以及对所得立体异构体的非对映选择性。值得注意的是，该体系不含金属且可循环使用。
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