Cao Hongda, Rupar Paul A
Department of Chemistry, The University of Alabama, Tuscaloosa, AL, 35487-0336, USA.
Chemistry. 2017 Oct 20;23(59):14670-14675. doi: 10.1002/chem.201703355. Epub 2017 Sep 27.
Thiophene is one of the most ubiquitous moieties in organic conjugated materials; however, furan, its oxygen congener, and furan derivatives have received comparatively less attention. This is primarily due to the intrinsic instability of furan and its tendency to decompose in the presence of oxygen and light. Incorporating furan into conjugated systems can confer many benefits, including increases in conjugation, improved solubility, and better transport properties. In this Concept Article, advances in furan-containing conjugated materials are presented. The impact of furan on the properties of conjugated materials is discussed, recent advances in synthetic methods are overviewed, and strategies for improving the stability of conjugated furans are detailed.
噻吩是有机共轭材料中最常见的基团之一;然而,其含氧类似物呋喃及其衍生物受到的关注相对较少。这主要是由于呋喃固有的不稳定性及其在氧气和光照存在下分解的倾向。将呋喃引入共轭体系可带来许多益处,包括共轭程度增加、溶解性改善以及传输性能提升。在这篇概念文章中,介绍了含呋喃共轭材料的进展。讨论了呋喃对共轭材料性能的影响,概述了合成方法的最新进展,并详细阐述了提高共轭呋喃稳定性的策略。