用于增强甘油电化学氧化的聚合物固定化混合多催化剂结构
Polymer-immobilized, hybrid multi-catalyst architecture for enhanced electrochemical oxidation of glycerol.
作者信息
Macazo Florika C, Hickey David P, Abdellaoui Sofiene, Sigman Matthew S, Minteer Shelley D
机构信息
Department of Chemistry, University of Utah, 315 S 1400 E, Salt Lake City, UT 84112, USA.
出版信息
Chem Commun (Camb). 2017 Sep 14;53(74):10310-10313. doi: 10.1039/c7cc05724e.
The development of a hybrid, tri-catalytic architecture is demonstrated by immobilizing MWCNTs, TEMPO-modified linear poly(ethylenimine) and oxalate decarboxylase on an electrode to enable enhanced electrochemical oxidation of glycerol. This immobilized, hybrid catalytic motif results in a synergistic 3.3-fold enhancement of glycerol oxidation and collects up to 14 electrons per molecule of glycerol.
通过将多壁碳纳米管、TEMPO修饰的线性聚乙烯亚胺和草酸脱羧酶固定在电极上，以实现甘油的增强电化学氧化，展示了一种混合三催化结构的开发。这种固定化的混合催化基序使甘油氧化协同增强了3.3倍，并且每分子甘油最多可收集14个电子。
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