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用于光催化应用的二维过渡金属二硫属化物与二氧化钛的纳米杂化物

Nanohybrids of Two-Dimensional Transition-Metal Dichalcogenides and Titanium Dioxide for Photocatalytic Applications.

作者信息

Rahmanian Elham, Malekfar Rasoul, Pumera Martin

机构信息

Division of Chemistry & Biological Chemistry, School of Physical and Mathematical Science, Nanyang Technological University, Singapore, 637371, Singapore.

Physics Department, Faculty of Basic Sciences, Tarbiat Modares University, P.O. Box 14115-175, Tehran, I. R. Iran.

出版信息

Chemistry. 2018 Jan 2;24(1):18-31. doi: 10.1002/chem.201703434. Epub 2017 Dec 4.

Abstract

The ever increasing need for renewable and clean energy resources as well as environmental concerns are considered as two serious challenges of today's society. Photocatalysis has proved to be a reliable and effective technology to overcome these issues. However, to bring the full potential of this approach into reality, two main hurdles of fast charge recombination and the limited visible light absorption should be tackled. To address these obstacles, nanocomposites based on titanium dioxide nanostructures and semiconducting two-dimensional transition-metal dichalcogenides have been developed and proven to be excellent photocatalysts. In this review, we will overview the recent developments on the fabrication and rational design of these nanocomposites both for hydrogen production and photocatalytic degradation of pollutants with emphasis on those appealing structures.

摘要

对可再生和清洁能源资源的需求不断增加以及环境问题被视为当今社会面临的两大严峻挑战。光催化已被证明是克服这些问题的可靠且有效的技术。然而,要充分发挥这种方法的潜力,需要解决快速电荷复合和可见光吸收有限这两个主要障碍。为应对这些障碍,基于二氧化钛纳米结构和二维半导体过渡金属二硫属化物的纳米复合材料已被开发出来,并被证明是优异的光催化剂。在本综述中,我们将概述这些纳米复合材料在制备和合理设计方面的最新进展,这些进展涉及用于制氢和光催化降解污染物,重点关注那些引人注目的结构。

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