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用于光催化析氢和污染物降解的二维过渡金属二硫属化物与石墨烯基三元复合材料

2D Transition Metal Dichalcogenides and Graphene-Based Ternary Composites for Photocatalytic Hydrogen Evolution and Pollutants Degradation.

作者信息

Chen Ying, Sun Hongqi, Peng Wenchao

机构信息

School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China.

Department of Chemical Engineering, Renai College of Tianjin University, Tianjin 301636, China.

出版信息

Nanomaterials (Basel). 2017 Mar 15;7(3):62. doi: 10.3390/nano7030062.

Abstract

Photocatalysis have attracted great attention due to their useful applications for sustainable hydrogen evolution and pollutants degradation. Transition metal dichalcogenides (TMDs) such as MoS₂ and WS₂ have exhibited great potential as cocatalysts to increase the photo-activity of some semiconductors. By combination with graphene (GR), enhanced cocatalysts of TMD/GR hybrids could be synthesized. GR here can act as a conductive electron channel for the transport of the photogenerated electrons, while the TMDs nanosheets in the hybrids can collect electrons and act as active sites for photocatalytic reactions. This mini review will focus on the application of TMD/GR hybrids as cocatalysts for semiconductors in photocatalytic reactions, by which we hope to provide enriched information of TMD/GR as a platform to develop more efficient photocatalysts for solar energy utilization.

摘要

光催化因其在可持续析氢和污染物降解方面的有用应用而备受关注。过渡金属二硫属化物(TMDs),如MoS₂和WS₂,作为助催化剂以提高某些半导体的光活性已展现出巨大潜力。通过与石墨烯(GR)结合,可以合成增强型的TMD/GR杂化助催化剂。此处的GR可作为光生电子传输的导电电子通道,而杂化物中的TMDs纳米片可以收集电子并作为光催化反应的活性位点。本综述将聚焦于TMD/GR杂化物作为半导体光催化反应助催化剂的应用,希望借此提供关于TMD/GR的丰富信息,作为开发更高效太阳能利用光催化剂的一个平台。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a4b/5388164/fb7c070ca088/nanomaterials-07-00062-g001.jpg

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