Fukui Norihito, Fujimoto Keisuke, Yorimitsu Hideki, Osuka Atsuhiro
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan.
Dalton Trans. 2017 Oct 10;46(39):13322-13341. doi: 10.1039/c7dt02815f.
Incorporation of planarized heteroatom(s) onto the porphyrin periphery is an effective approach to create porphyrin-based functional materials. In the last three decades, such an "embedding heteroatom" strategy has been actively explored in order to realize attractive electronic, optical, and electrochemical properties. This review aims to cover a variety of synthetic methodologies that have been developed for the construction of heteroatom-embedded porphyrins. Moreover, we also summarize their structure-property relationships as well as possible applications in various research fields including artificial photosynthesis, molecular engineering, organic electronics, and bioimaging.
将平面杂原子引入卟啉外围是制备基于卟啉的功能材料的有效方法。在过去三十年中，人们积极探索这种“嵌入杂原子”策略，以实现吸引人的电子、光学和电化学性质。本综述旨在涵盖已开发的用于构建嵌入杂原子卟啉的各种合成方法。此外，我们还总结了它们的结构-性质关系以及在包括人工光合作用、分子工程、有机电子学和生物成像在内的各个研究领域中的可能应用。
