Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan.
Chem Soc Rev. 2015 Feb 21;44(4):943-69. doi: 10.1039/c3cs60443h.
Conjugated porphyrin arrays that possess delocalised electronic networks have, for the most part, been assembled by using alkene or alkyne type bridging units or by directly connecting individual porphyrin chromophores with multiple bonds to form fused porphyrin arrays. Throughout the last two decades, such conjugated porphyrin arrays have been actively explored due to their attractive electronic, optical and electrochemical properties. This review aims to cover the multitude of synthetic methodologies that have been developed for the construction of conjugated porphyrin arrays as well as to summarise their structure-property relationships and use in various applications such as near infrared (NIR) dyes, nonlinear optical materials and electron-conducting molecular wires.
具有离域电子网络的共轭卟啉阵列，在大多数情况下，是通过使用烯烃或炔烃类型的桥接单元或通过直接用多个键将单个卟啉生色团连接起来形成稠合卟啉阵列来组装的。在过去的二十年中，由于它们具有吸引人的电子、光学和电化学性质，这种共轭卟啉阵列一直受到积极的探索。本综述旨在涵盖为构建共轭卟啉阵列而开发的多种合成方法，并总结它们的结构-性质关系及其在各种应用中的用途，如近红外 (NIR) 染料、非线性光学材料和电子传导分子线。
