钙芪配合物：结构与双重反应性
Calcium stilbene complexes: structures and dual reactivity.
作者信息
Causero Andrea, Elsen Holger, Ballmann Gerd, Escalona Ana, Harder Sjoerd
机构信息
Inorganic and Organometallic Chemistry, University Erlangen-Nürnberg, Egerlandstrasse 1, 91058 Erlangen, Germany.
出版信息
Chem Commun (Camb). 2017 Sep 19;53(75):10386-10389. doi: 10.1039/c7cc05792j.
PMID:28876007
Abstract
Addition of a calcium hydride complex to diphenylacetylene gave a complex in which the stilbene dianion symmetrically bridges two Ca ions. DFT calculations discuss the effect of the metal stilbene coordination. The stilbene complex reacts as a base (with H) or an electron donor (with I) and catalyzes the reduction of diphenylacetylene.
摘要
向二苯乙炔中加入氢化钙配合物得到一种配合物，其中芪二价阴离子对称地桥连两个钙离子。密度泛函理论计算讨论了金属芪配位的影响。芪配合物作为碱（与氢反应）或电子供体（与碘反应）起作用，并催化二苯乙炔的还原反应。
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