单壁碳纳米管分离方法与技术的综合综述
A Comprehensive Review on Separation Methods and Techniques for Single-Walled Carbon Nanotubes.
作者信息
Komatsu Naoki, Wang Feng
机构信息
Department of Chemistry, Shiga University of Medical Science, Seta, Otsu, Shiga 520-2192, Japan.
出版信息
Materials (Basel). 2010 Jun 30;3(7):3818-3844. doi: 10.3390/ma3073818.
Structural control of single-walled carbon nanotubes (SWNTs) is attracting enormous interest in view of their applications to nanoelectronics and nanooptics. Actually, more than 200 papers regarding separation of SWNTs have been published since 1998. In this review, they are classified into the following five sections according to the separation methods; electrophoresis, centrifugation, chromatography, selective solubilization and selective reaction. In each method, all literature is summarized in tables showing the separated objects (metallic/semiconducting (M/S), length, diameter, (, ) structure and/or handedness), the production process of the used SWNTs (CoMoCAT, HiPco, arc discharge and/or laser vaporization) and the employed chemicals, such as detergents and polymers. Changes in annual number of publications related to this subject are also discussed.
鉴于单壁碳纳米管(SWNTs)在纳米电子学和纳米光学领域的应用,其结构控制正引起人们极大的兴趣。实际上,自1998年以来,已经发表了200多篇关于单壁碳纳米管分离的论文。在这篇综述中,根据分离方法将它们分为以下五个部分:电泳、离心、色谱、选择性溶解和选择性反应。在每种方法中,所有文献都汇总在表格中,展示了分离对象(金属/半导体(M/S)、长度、直径、(,)结构和/或手性)、所用单壁碳纳米管的生产过程(CoMoCAT、HiPco、电弧放电和/或激光蒸发)以及所使用的化学物质,如洗涤剂和聚合物。还讨论了与该主题相关的年出版物数量的变化。