Fouassier Jean-Pierre, Morlet-Savary Fabrice, Lalevée Jacques, Allonas Xavier, Ley Christian
Department of Photochemistry, CNRS, University of Haute Alsace, ENSCMu, 3 rue Alfred Werner, 68093 Mulhouse, Cedex, France.
Materials (Basel). 2010 Dec 2;3(12):5130-5142. doi: 10.3390/ma3125130.
A short but up-to-date review on the role of dyes in the photoinitiation processes of polymerization reactions is presented. Radical and cationic reactions are largely encountered in the radiation curing and the imaging areas for use in traditional coating applications as well as in high tech sectors such as nanofabrication, computer-to-plate processing, laser direct imaging, manufacture of optical elements, etc. Recent promising developments concerned with the introduction of the silyl radical chemistry that enhances the polymerization efficiency are also discussed.
本文对染料在聚合反应光引发过程中的作用进行了简短但最新的综述。自由基反应和阳离子反应在辐射固化和成像领域中广泛存在，可用于传统涂层应用以及纳米制造、计算机直接制版处理、激光直接成像、光学元件制造等高精尖领域。本文还讨论了最近有关引入硅基自由基化学以提高聚合效率的一些有前景的进展。
