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聚合物与光:爱恨交织的关系。

Polymers and light: a love-hate relationship.

作者信息

Weerasinghe M A Sachini N, Nwoko Tochukwu, Konkolewicz Dominik

机构信息

Department of Chemistry and Biochemistry, Miami University 651 E High St Oxford OH 45056 USA

出版信息

Chem Sci. 2025 Mar 17;16(13):5326-5352. doi: 10.1039/d5sc00997a. eCollection 2025 Mar 26.

Abstract

The study of the interaction between polymers and light has significantly bloomed over the past few years in various fundamental research and applications. The relationship between polymers and light can be beneficial (we refer to this as "love") or be destructive (we refer to this as "hate"). It is important to understand the nature of both these love and hate relationships between polymers and light to apply these concepts in various future systems, to surpass performance of existing materials, or to mitigate some problems associated with polymers. Therefore, this perspective highlights both the photophilic (, photopolymerization, rate modulation, temporal/spatial control, drug delivery, waste management, photo functionalization, and photo-enhanced depolymerization) and photophobic (, photodegradation, discoloration, optical density, and loss of functionality) nature of polymers.

摘要

在过去几年中,聚合物与光相互作用的研究在各种基础研究和应用中显著兴起。聚合物与光之间的关系可能是有益的(我们称之为“爱”),也可能是破坏性的(我们称之为“恨”)。了解聚合物与光之间这些“爱”与“恨”关系的本质,对于在各种未来系统中应用这些概念、超越现有材料的性能或减轻与聚合物相关的一些问题至关重要。因此,本文综述突出了聚合物的亲光性(如光聚合、速率调制、时空控制、药物递送、废物管理、光功能化和光增强解聚)和憎光性(如光降解、变色、光密度和功能丧失)本质。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/543d/11938829/033963cc21d5/d5sc00997a-f1.jpg

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