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用于超灵敏化学气相传感的纳米复合网络薄膜可拉伸电子传感器。

Stretchable Electronic Sensors of Nanocomposite Network Films for Ultrasensitive Chemical Vapor Sensing.

作者信息

Yan Hong, Zhong Mengjuan, Lv Ze, Wan Pengbo

机构信息

Center of Advanced Elastomer Materials, State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing, 100029, P. R. China.

出版信息

Small. 2017 Nov;13(41). doi: 10.1002/smll.201701697. Epub 2017 Sep 12.

Abstract

A stretchable, transparent, and body-attachable chemical sensor is assembled from the stretchable nanocomposite network film for ultrasensitive chemical vapor sensing. The stretchable nanocomposite network film is fabricated by in situ preparation of polyaniline/MoS (PANI/MoS ) nanocomposite in MoS suspension and simultaneously nanocomposite deposition onto prestrain elastomeric polydimethylsiloxane substrate. The assembled stretchable electronic sensor demonstrates ultrasensitive sensing performance as low as 50 ppb, robust sensing stability, and reliable stretchability for high-performance chemical vapor sensing. The ultrasensitive sensing performance of the stretchable electronic sensors could be ascribed to the synergistic sensing advantages of MoS and PANI, higher specific surface area, the reliable sensing channels of interconnected network, and the effectively exposed sensing materials. It is expected to hold great promise for assembling various flexible stretchable chemical vapor sensors with ultrasensitive sensing performance, superior sensing stability, reliable stretchability, and robust portability to be potentially integrated into wearable electronics for real-time monitoring of environment safety and human healthcare.

摘要

一种可拉伸、透明且可附着于身体的化学传感器由用于超灵敏化学蒸汽传感的可拉伸纳米复合网络薄膜组装而成。该可拉伸纳米复合网络薄膜是通过在二硫化钼(MoS)悬浮液中原位制备聚苯胺/二硫化钼(PANI/MoS)纳米复合材料,并同时将纳米复合材料沉积到预应变弹性体聚二甲基硅氧烷基底上制成的。所组装的可拉伸电子传感器展现出低至50 ppb的超灵敏传感性能、强大的传感稳定性以及用于高性能化学蒸汽传感的可靠拉伸性。可拉伸电子传感器的超灵敏传感性能可归因于二硫化钼和聚苯胺的协同传感优势、更高的比表面积、相互连接网络的可靠传感通道以及有效暴露的传感材料。有望在组装具有超灵敏传感性能、卓越传感稳定性、可靠拉伸性和强大便携性的各种柔性可拉伸化学蒸汽传感器方面大有可为,这些传感器有可能集成到可穿戴电子产品中,用于实时监测环境安全和人类健康。

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