温和的脱羧C-H烷基化反应：对耐溶剂钌（II）多米诺反应机理的计算洞察
Mild Decarboxylative C-H Alkylation: Computational Insights for Solvent-Robust Ruthenium(II) Domino Manifold.
作者信息
Kumar N Y Phani, Rogge Torben, Yetra Santhivardhana Reddy, Bechtoldt Alexander, Clot Eric, Ackermann Lutz
机构信息
Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077, Göttingen, Germany.
Institut Charles Gerhardt Montpellier, UMR 5253 CNRS-UM-ENSCM, Université de Montpellier, cc 1501, Place Eugène Bataillon, 34095, Montpellier, Cedex 5, France.
出版信息
Chemistry. 2017 Dec 11;23(69):17449-17453. doi: 10.1002/chem.201703680. Epub 2017 Oct 18.
Computational studies on decarboxylative C-H alkenylations provided key insights into the solvent-robust nature of C-H activation/decarboxylation domino reactions. These properties were exploited for ruthenium(II)-catalyzed C-H alkylations by a decarboxylative process with ample scope under copper-free and silver-free reaction conditions.
关于脱羧C-H烯基化反应的计算研究为C-H活化/脱羧多米诺反应的溶剂稳定性本质提供了关键见解。这些性质被用于在无铜和无银反应条件下通过脱羧过程进行钌（II）催化的C-H烷基化反应，其适用范围广泛。
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