Kuciński K, Hreczycho G
Faculty of Chemistry, Adam Mickiewicz University in Poznań, Ul. Umultowska 89b, 61-614, Poznań, Poland.
ChemSusChem. 2017 Dec 8;10(23):4695-4698. doi: 10.1002/cssc.201701648. Epub 2017 Nov 2.
This paper demonstrates the first highly chemoselective syntheses of various borasiloxanes from hydroboranes and silanols, achieved through catalyst-free dehydrogenative coupling at room temperature. This green protocol, which uses easily accessible reagents, allows for the obtaining of borasiloxanes under air atmosphere and solvent-free conditions.
本文展示了通过室温下无催化剂脱氢偶联，首次从硼烷和硅醇高度化学选择性合成各种硼硅氧烷。这种绿色方法使用易于获取的试剂，能够在空气气氛和无溶剂条件下获得硼硅氧烷。
