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[苦杏仁的酸败与变质论析]

[Rancidness of Armeniacae Semen Amarum involving Bianzhuang Lunzhi].

作者信息

Gong Jian-Ting, Zhao Li-Ying, Rudolf Bauer, Mi Wen-Juan, Li Yang, Li Jia-Hui, Ren Zhi-Yu, Xu Dong, Zhao Ting, Yan Yong-Hong

机构信息

School of Chinese Pharmacy, Beijing University of Chinese Medicine, Beijing 100102, China.

Institute of Pharmaceutical Science, University of Graz, Graz 8010, Austria.

出版信息

Zhongguo Zhong Yao Za Zhi. 2016 Dec;41(23):4375-4381. doi: 10.4268/cjcmm20162314.

Abstract

This article aims to compare the qualities of Armeniacae Semen Amarum before and after rancidness, in order to study the rancidness of Armeniacae Semen Amarum. In the experiment, content of fatty oil, acid value and peroxide value were determined before and after rancidness,respectively. Meanwhile, HPLC, GC-MS were utilized to analyze laetrile and fatty acid components. Besides, colorimeter and e-nose were introduced to quantify and compare "color and odor". A correlation analysis was conducted on the above results. The results showed that color of post-rancidness Armeniacae Semen Amarum changed from yellow to brown, with sour and lower content of laetrile. On the contrary, acid and peroxide values increased significantly, with changes in fatty acid component. There was a considerable correlation between appearance characteristics and changes in internal quality. The "sensory analysis-quality identification system" can provide a certain scientific basis for prediction of the content of chemical components in traditional Chinese medicine, preliminary judgment of quality of traditional Chinese medicine and real-time quality monitoring, which offers us novel ideas and reference for storage principles of traditional Chinese medicines of "pre-event prediction, during-event intervention and post-event identification".

摘要

本文旨在比较苦杏仁在酸败前后的品质,以研究苦杏仁的酸败情况。实验分别测定了苦杏仁酸败前后的脂肪油含量、酸值和过氧化值。同时,采用高效液相色谱法(HPLC)、气相色谱-质谱联用法(GC-MS)分析苦杏仁苷和脂肪酸成分。此外,引入色差仪和电子鼻对“色泽和气味”进行量化和比较。对上述结果进行相关性分析。结果表明,酸败后的苦杏仁颜色由黄色变为棕色,有酸味且苦杏仁苷含量降低。相反,酸值和过氧化值显著增加,脂肪酸成分发生变化。外观特征与内在品质变化之间存在显著相关性。“感官分析-质量识别系统”可为中药化学成分含量预测、中药质量初步判断及实时质量监测提供一定的科学依据,为中药“事前预测、事中干预、事后鉴定”的储存原则提供新思路和参考。

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