Mohaghegh Farid, Akhbari Kamran, Phuruangrat Anukorn
School of Chemistry, College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, Islamic Republic of Iran.
School of Chemistry, College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, Islamic Republic of Iran.
Ultrason Sonochem. 2018 Jan;40(Pt A):594-600. doi: 10.1016/j.ultsonch.2017.08.009. Epub 2017 Aug 10.
Microstructures of [Tl(μ-ATA)] (1), [HATA=2-aminoterephthalic acid], supramolecular polymer was synthesized by sonochemical process (1S) and used as new precursor for preparation pure phase of thallium(III) oxide microstructures. [Tl(μ-dcpa)] (2), [Hdcpa=2,4-dichlorophenoxyacetic acid], is another supramolecular polymer which was synthesized by green sonochemical (2S) and mechanochemical (2M) processes. These two samples of 2 were also used for preparation of thallium nanomaterials. Both processes on 2 were successful but mixture of Tl, TlO and TlCl nanostructures with various morphologies from 2S and mixture of TlO and TlCl nanoparticles from 2M were obtained. These micro and nanostructures were characterized by IR spectroscopy, X-ray powder diffraction (XRD) and Scanning Electron Microscopy (SEM).
通过声化学过程（1S）合成了[Tl(μ-ATA)]（1），[HATA = 2-氨基对苯二甲酸]的超分子聚合物，并将其用作制备纯相氧化铊微观结构的新前驱体。[Tl(μ-dcpa)]（2），[Hdcpa = 2,4-二氯苯氧基乙酸]，是另一种通过绿色声化学（2S）和机械化学（2M）过程合成的超分子聚合物。这两个样品2也用于制备铊纳米材料。对2的两种过程均成功，但从2S获得了具有各种形态的Tl、TlO和TlCl纳米结构的混合物，从2M获得了TlO和TlCl纳米颗粒的混合物。这些微观和纳米结构通过红外光谱、X射线粉末衍射（XRD）和扫描电子显微镜（SEM）进行了表征。
