Wang Rui, Li Yan, Jin Ruo-Xing, Wang Xi-Sheng
Department of Chemistry , University of Science and Technology of China , 96 Jinzhai Road , Hefei , Anhui 230026 , China . Email:
Chem Sci. 2017 May 1;8(5):3838-3842. doi: 10.1039/c7sc00250e. Epub 2017 Mar 15.
Copper-catalyzed selective coupling of C(sp)-H bonds with C(sp)-H bonds has been developed. An aniline module was used as a directing group to generate an aminyl radical, which selectively cleaves the secondary and tertiary C(sp)-H bonds a 1,5-HAT process to forge six-membered carbocyclic rings.
已开发出铜催化的C(sp) -H键与C(sp) -H键的选择性偶联反应。使用苯胺模块作为导向基团来生成氨基自由基，该自由基通过1,5-氢原子转移（1,5-HAT）过程选择性地裂解仲碳和叔碳C(sp) -H键，以构建六元碳环。
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