Binder Mareike, Schrenk Claudio, Block Theresa, Pöttgen Rainer, Schnepf Andreas
Institut für Anorganische Chemie, Universität Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany.
Chem Commun (Camb). 2017 Oct 12;53(82):11314-11317. doi: 10.1039/c7cc07029b.
The reaction of the metalloid tin cluster [Sn(Hyp)] with (PhP)Au-SHyp (Hyp = Si(SiMe)) gave an intermetalloid cluster [AuSn(Hyp)]1, which is the longest intermetalloid chain compound of tin to date. 1 shows a structural resemblance to binary AuSn phases, which is expected for intermetalloid clusters.
类金属锡簇合物[Sn(Hyp)]与(PhP)Au - SHyp（Hyp = Si(SiMe)）反应生成了类金属间簇合物[AuSn(Hyp)]₁，它是迄今为止最长的锡类金属间链状化合物。1与二元AuSn相具有结构相似性，这对于类金属间簇合物来说是预期的。
