Feng Shi, Xu Hong, Zhang Chong, Chen Yu, Zeng Jinghui, Jiang Donglin, Jiang Jia-Xing
Key Laboratory of Applied Surface and Colloid Chemistry (Shaanxi Normal University), Ministry of Education, Key Laboratory for Macromolecular Science of Shaanxi Province, School of Materials Science and Engineering, Shaanxi Normal University, Xi'an 710062, Shaanxi, P. R. China.
Chem Commun (Camb). 2017 Oct 12;53(82):11334-11337. doi: 10.1039/c7cc07024a.
A highly redox-active building block, bicarbazole, is developed as a monomer for designing crystalline porous covalent organic frameworks and is successfully integrated to the vertices of microporous tetragonal frameworks, leading to densely aligned redox-active arrays. The frameworks with large porosity and high accessibility of the redox-active sites exhibit synergistic structural effects and ultrahigh-performance energy storage.
一种具有高氧化还原活性的结构单元——联咔唑，被开发用作设计晶体多孔共价有机框架的单体，并成功整合到微孔四方框架的顶点，形成密集排列的氧化还原活性阵列。具有大孔隙率和氧化还原活性位点高可达性的框架展现出协同结构效应和超高性能储能。
