Bose Anima, Mal Prasenjit
School of Chemical Sciences, National Institute of Science Education and Research (NISER), HBNI, Bhubaneswar, PO Bhimpur-Padanpur, Via Jatni, District Khurda, Odisha 752050, India.
Chem Commun (Camb). 2017 Oct 12;53(82):11368-11371. doi: 10.1039/c7cc06267b.
An unprecedented C-H mononitration of indolines either at the -C or -C positions under mild condition is reported here. The roles of multiple weak interactions and factors such as steric factors, electronic effects, cation-π interactions, and solvent polarity were established, and we achieved a 100% regioselective electrophilic aromatic (EArS) nitration using Cu(NO) or AgNO.
本文报道了在温和条件下，吲哚啉在-C或-C位置前所未有的C-H单硝化反应。确定了多种弱相互作用以及空间因素、电子效应、阳离子-π相互作用和溶剂极性等因素的作用，并且我们使用Cu(NO)或AgNO实现了100%区域选择性亲电芳香（EArS）硝化反应。
