Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, Zhejiang, China.
Nanoscale. 2017 Oct 19;9(40):15477-15483. doi: 10.1039/c7nr04341d.
Poor light extraction efficiency (LEE) has been one of the major challenges responsible for the low external quantum efficiency of AlGaN-based ultraviolet light emitting Diodes (UV-LEDs). In this study, AlGaN nanostructure arrays were fabricated using a large-scale nanosphere self-assembly technique followed by reactive ion etching, and the transmission property of the AlGaN thin film and the photoluminescence (PL) behavior of AlGaN/GaN multiple-quantum-wells (MQWs) were investigated. A 90% light transmission value was obtained for the AlGaN thin film and a 2.5-fold increase in the band edge luminescence of the MQWs were obtained with an optimized nanostructure periodicity. Essentially, a general rule of periodicity-MQW emission wavelength matching criteria-was provided. Both the light transmission properties of the AlGaN/AlN/sapphire thin film and the photoluminescence (PL) behavior of the AlGaN/GaN MQWs contribute to an improved understanding of the light extraction mechanism of PhC patterned UV-LEDs. Raman spectra also demonstrated the strain relaxation inside the MQW after nanostructure fabrication and thermal annealing. This study provides a pathway towards higher efficiency UV-LEDs with the help of a periodicity-wavelength matched nanostructure array.
光提取效率(LEE)低一直是导致基于 AlGaN 的紫外发光二极管(UV-LED)外量子效率低的主要挑战之一。在这项研究中,使用大规模的纳米球自组装技术和反应离子刻蚀来制造 AlGaN 纳米结构阵列,并研究了 AlGaN 薄膜的传输特性和 AlGaN/GaN 多量子阱(MQWs)的光致发光(PL)行为。对于 AlGaN 薄膜,获得了 90%的光透射值,并且通过优化的纳米结构周期性,获得了 MQWs 的带边发光强度增加了 2.5 倍。本质上,提供了一个周期性-MQW 发射波长匹配标准的通用规则。AlGaN/AlN/蓝宝石薄膜的光传输特性和 AlGaN/GaN MQWs 的光致发光(PL)行为都有助于更好地理解 PhC 图案化 UV-LED 的光提取机制。拉曼光谱也证明了纳米结构制造和热退火后 MQW 内部的应变弛豫。本研究通过周期性波长匹配的纳米结构阵列为提高 UV-LED 的效率提供了一种途径。