Jin Jiaye, Li Wei, Liu Yuhong, Wang Guanjun, Zhou Mingfei
Department of Chemistry , Collaborative Innovation Center of Chemistry for Energy Materials , Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials , Fudan University , Shanghai 200433 , China . Email:
Chem Sci. 2017 Sep 1;8(9):6594-6600. doi: 10.1039/c7sc02472j. Epub 2017 Jul 17.
The cation complexes [ArBO], [ArBO], [ArBO] and [ArBO] were prepared a laser vaporization supersonic ion source in the gas phase. Their vibrational spectra were measured mass-selected infrared photodissociation spectroscopy. Spectroscopy combined with quantum chemical calculations revealed that the [ArBO], [ArBO] and [ArBO] cation complexes have planar structures each involving an aromatic boroxol ring and an argon-boron covalent bond. In contrast, the [ArBO] cation is characterized to be a weakly bound complex with a BO chain structure.
阳离子配合物[ArBO]、[ArBO]、[ArBO]和[ArBO]是在气相中通过激光蒸发超声离子源制备的。它们的振动光谱通过质量选择红外光解离光谱进行测量。光谱学与量子化学计算相结合表明，[ArBO]、[ArBO]和[ArBO]阳离子配合物具有平面结构，每个结构都包含一个芳族硼氧环和一个氩-硼共价键。相比之下，[ArBO]阳离子的特征是具有BO链结构的弱结合配合物。
