铁催化的α-重氮酯对 Si-H 键的卡宾插入反应。
Iron-Catalyzed Carbene Insertion Reactions of α-Diazoesters into Si-H Bonds.
机构信息
Département de Chimie, Université Laval , 1045 avenue de la Médecine, Québec, QC G1V 0A6, Canada.
出版信息
Org Lett. 2017 Nov 3;19(21):5736-5739. doi: 10.1021/acs.orglett.7b02488.
PMID:29028345
Abstract
An efficient iron-catalyzed carbene insertion reaction of α-diazo carbonyl compounds into the Si-H bond was developed. A wide range of α-silylesters was obtained in high yields (up to 99%) from α-diazoesters using a simple iron(II) salt as catalyst.
摘要
发展了一种高效的铁催化α-重氮羰基化合物插入 Si-H 键的反应。使用简单的二价铁盐作为催化剂，从α-重氮酯可以高收率（高达 99%）得到广泛的α-硅酯。
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