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铁的沉积物指纹-铁形态作为地球化学示踪剂。

Iron's fingerprint of deposits-iron speciation as a geochemical marker.

机构信息

Faculty of Chemistry, Department of Analytical Chemistry, Adam Mickiewicz University, 89b Umultowska Street, 61-614, Poznan, Poland.

出版信息

Environ Sci Pollut Res Int. 2018 Jan;25(1):242-248. doi: 10.1007/s11356-017-0387-2. Epub 2017 Oct 13.

DOI:10.1007/s11356-017-0387-2
PMID:29030832
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5756553/
Abstract

The article describes the studies of the iron speciation (the occurrence of Fe(II), Fe(III), and complexed iron) in acid leachable fraction of deposits. The speciation of iron was diverse for deposits of different origins and was the specific "fingerprint"-marker of deposition processes. The higher occurrence of Fe(II) may be connected with decantation which has been observed for lake sediments, the majority of Fe(III) with upper flow regime erosion-deposition processes, observed for river sediment deposition during flood episodes. As verification for this hypothesis, the explanation for the iron speciation in the different river sediment samples has been used.

摘要

本文描述了沉积物酸可提取部分中铁形态(Fe(II)、Fe(III) 和配合态铁)的研究。不同成因沉积物中铁的形态多种多样,是特定的沉积过程“指纹”标记。较高的 Fe(II)含量可能与沉降作用有关,沉降作用在湖泊沉积物中较为常见;较高的 Fe(III)含量可能与上流水流侵蚀-沉积作用有关,这种作用在洪水期间河流沉积物的沉积过程中较为常见。为了验证这一假设,本文还对不同河流沉积物样品中铁形态的成因进行了分析。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d76/5756553/3483dc5afee0/11356_2017_387_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d76/5756553/483b835a04eb/11356_2017_387_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d76/5756553/e34382f84da9/11356_2017_387_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d76/5756553/d81b74536aab/11356_2017_387_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d76/5756553/3483dc5afee0/11356_2017_387_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d76/5756553/483b835a04eb/11356_2017_387_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d76/5756553/e34382f84da9/11356_2017_387_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d76/5756553/d81b74536aab/11356_2017_387_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d76/5756553/3483dc5afee0/11356_2017_387_Fig4_HTML.jpg

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Talanta. 2015 Jan;132:591-9. doi: 10.1016/j.talanta.2014.10.009. Epub 2014 Oct 19.
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The evolution of December 2004 tsunami deposits: temporal and spatial distribution of potentially toxic metalloids.2004 年 12 月海啸沉积物的演化:潜在有毒类金属元素的时空分布。
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Isotopic fingerprints of anthropogenic molybdenum in lake sediments.
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Environ Sci Technol. 2012 Oct 16;46(20):10934-40. doi: 10.1021/es3019379. Epub 2012 Oct 4.
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Uptake and release of cerium during Fe-oxide formation and transformation in Fe(II) solutions.在 Fe(II)溶液中形成和转化过程中,铈的摄取和释放。
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