School of Chemistry and Environmental Engineering, Wuhan Institute of Technology , Wuhan 430205, China.
Institute of Organic Chemistry, RWTH Aachen University , Landoltweg 1, D-52056 Aachen, Germany.
Org Lett. 2017 Nov 3;19(21):5916-5919. doi: 10.1021/acs.orglett.7b02911.
An efficient protocol for the copper-catalyzed preparation of aryl dithiocarbamates from aryl iodides and inexpensive, environmentally benign tetraalkylthiuram disulfides was developed. The features of mild reaction conditions, high yields, and broad substrate scope render this new approach synthetically attractive for the preparation of potentially biologically active compounds.
开发了一种从芳基碘化物和廉价、环境友好的四烷基硫代秋兰姆二硫化物制备芳基二硫代氨基甲酸盐的高效铜催化方法。该方法具有反应条件温和、产率高、底物范围广的特点，为潜在生物活性化合物的制备提供了一种有吸引力的合成方法。
