由供体-受体相互作用控制的聚合物自组装光解作用。
Photolysis of polymeric self-assembly controlled by donor-acceptor interaction.
作者信息
Qian Tingjuan, Chen Feiyi, Chen Yulan, Wang Yi-Xuan, Hu Wenping
机构信息
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Science, Tianjin University and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China.
出版信息
Chem Commun (Camb). 2017 Aug 22;53(86):11822-11825. doi: 10.1039/c7cc07560j.
A photodegradable supramolecular polymer was constructed using cucurbit[8]uril (CB[8]) and an alkoxyanthracene guest. The monomeric unit was photostable because of the intramolecular donor-acceptor interaction. However, upon complexation with CB[8], the photolysis of alkoxyanthracene was enhanced, which endowed the supramolecular polymer with great photoreactivity.
使用葫芦[8]脲（CB[8]）和烷氧基蒽客体构建了一种可光降解的超分子聚合物。由于分子内供体-受体相互作用，单体单元具有光稳定性。然而，与CB[8]络合后，烷氧基蒽的光解增强，这赋予了超分子聚合物很大的光反应活性。
Zotero 插件