中心对称的(Hdima)[GeBO(OH)]和非中心对称的NaGaBO(OH)：开放框架硼锗酸盐和硼镓酸盐的溶剂热/表面活性剂热合成
Centrosymmetric (Hdima)[GeBO(OH)] and Noncentrosymmetric NaGaBO(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate.
作者信息
Yu Su-Juan, Gu Xiang-Yu, Deng Ting-Ting, Huang Jian-Hao, Cheng Jian-Wen, Yang Guo-Yu
机构信息
College of Chemistry and Life Sciences, Zhejiang Normal University , Jinhua, Zhejiang 321004, China.
MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology , Beijing 100081, China.
出版信息
Inorg Chem. 2017 Nov 6;56(21):12695-12698. doi: 10.1021/acs.inorgchem.7b02328.
Under solvothermal/surfactant-thermal conditions, two new open-framework borogermanate and galloborate, centrosymmetric (Hdima)[GeBO(OH)] (1; dima = dimethylamine) and noncentrosymmetric NaGaBO(OH) (2), were obtained and characterized. Compound 1 contains an unusual basket-shaped GeBO(OH) cluster and displays a 3D open-framework layered structure. Compound 2 shows an interrupted 3,4-connected network constructed by alternately linked BO units and Ga ions and displays weak second-harmonic-generation response.
在溶剂热/表面活性剂热条件下，获得并表征了两种新型开放框架硼锗酸盐和硼镓酸盐，即中心对称的(Hdima)[GeBO(OH)]（1；dima = 二甲胺）和非中心对称的NaGaBO(OH)（2）。化合物1包含一个不寻常的篮状GeBO(OH)簇，并呈现出三维开放框架层状结构。化合物2展示了由交替连接的BO单元和Ga离子构建的间断的3,4-连接网络，并表现出较弱的二次谐波产生响应。
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