Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University , Nanjing 210023, China.
Org Lett. 2017 Nov 3;19(21):5940-5943. doi: 10.1021/acs.orglett.7b02931.
A general method for selective ortho C-H arylation of ketone, with boron reagent enabled by rhodium complexes with excellent yields, is developed. The transformation is characterized by the use of air-stable Rh catalyst, high monoarylation selectivity, and excellent yields of most of the substrates.
发展了一种酮的选择性邻位 C-H 芳基化的通用方法，该方法使用硼试剂和铑配合物作为催化剂，具有优异的收率。该转化的特点是使用空气稳定的 Rh 催化剂、高单芳基化选择性和大多数底物的优异收率。
