Peng Tsung-Ren, Tong Lun-Tao, Liu Tsang-Sen, Zhan Wen-Jun, Chiang Li-Wei, Lu Wan-Chung, Chen Chi-Tsun
Department of Soil and Environmental Sciences, National Chung Hsing University, Taichung, 40227, Taiwan.
Industrial Technology Research Institute, Hsinchu, 31040, Taiwan.
J Mass Spectrom. 2018 Jan;53(1):48-57. doi: 10.1002/jms.4038.
This study is to develop an isotopic catchment-effect index (CEI) connecting the physiographic characteristics of stream catchments. A CEI, describing the extent of difference in stable water isotopic compositions (δ values) between stream water and local precipitation at any given sampling site, can help in judging whether water resource management should be focused on upstream regions of streams or local hydrology issues. To establish the isotopic CEI, this study measured δ values of stream water and derived δ O of local precipitation based on regional isotopic altitude gradient at montane catchments of various sizes. Results indicate that the CEI is strongly related to catchment physiographic characteristics, such as length of main stream, mean area, mean elevation, perimeter, and slope. These characteristics are considered important indices of streamflow. Based on mathematical regression modeling describing the relationships between CEI and respective physiographic factors, CEI values can predict respective physiographic factors and vice versa. Moreover, according to the multiple equations derived in this study, catchments of larger size and steeper slope give elevated CEI values while greater stream length reduces the CEI's value. A greater CEI value indicates that local stream water is principally sourced from upstream reaches rather than contributions from local precipitation. In addition, CEI values are greater in winter than in summer resulting from monsoon effect. Consequently, this study establishes CEI as a useful descriptor of the physiographic characteristics of catchments.
本研究旨在开发一种连接河流水集水区地貌特征的同位素集水效应指数(CEI)。CEI描述了在任何给定采样点处溪水与当地降水之间稳定水同位素组成(δ值)的差异程度,有助于判断水资源管理应关注溪流的上游区域还是当地水文问题。为建立同位素CEI,本研究测量了溪水的δ值,并根据不同大小山地集水区的区域同位素海拔梯度推导了当地降水的δO。结果表明,CEI与集水区地貌特征密切相关,如主流长度、平均面积、平均海拔、周长和坡度。这些特征被认为是径流的重要指标。基于描述CEI与各地貌因素之间关系的数学回归模型,CEI值可以预测各地貌因素,反之亦然。此外,根据本研究推导的多个方程,面积较大且坡度较陡的集水区CEI值较高,而较大的溪流长度会降低CEI值。较高的CEI值表明当地溪水主要来自上游河段,而非当地降水的贡献。此外,由于季风效应,冬季的CEI值高于夏季。因此,本研究将CEI确立为集水区地貌特征的有用描述符。