用于催化碳-碳和碳-杂原子交叉偶联反应的亚纳米金属簇
Sub-nanometre metal clusters for catalytic carbon-carbon and carbon-heteroatom cross-coupling reactions.
作者信息
Leyva-Pérez A
机构信息
Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas, Avda. de los Naranjos s/n, 46022, Valencia, Spain.
出版信息
Dalton Trans. 2017 Nov 28;46(46):15987-15990. doi: 10.1039/c7dt03203j.
Catalytic cross-coupling reactions are fundamental transformations in modern organic synthesis. Traditionally based on single-atom transition metal complex catalysts, the use of sub-nanometre metal clusters with enhanced redox and coordinating properties may lead to more efficient catalysts. Recent developments and potential new directions of catalytic sub-nanometre metal clusters for cross-coupling reactions are briefly discussed here.
催化交叉偶联反应是现代有机合成中的基本转化反应。传统上基于单原子过渡金属络合物催化剂，使用具有增强氧化还原和配位性质的亚纳米金属簇可能会产生更高效的催化剂。本文简要讨论了用于交叉偶联反应的催化亚纳米金属簇的最新进展和潜在新方向。
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