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用于义齿基托衬里材料的聚氟乙烯共聚物的性能(作者译)

[Properties of polyfluoroethylene-copolymers for the denture base lining material (author's transl)].

作者信息

Masuhara E, Nagata K, Satoh M, Watanabe A, Bannai N, Imai Y

出版信息

Shika Rikogaku Zasshi. 1979 Apr;20(50):115-20.

PMID:290706
Abstract

Silicone rubber is conventionally used as a lining soft material for denture base. However it still has some properties to be improved, such as poor adhesive strenth with acrylic resin, discoloration, degradation and growth of candida. We attempted to apply chemically-stable polyfluoroethylene-copolymers for this purpose. The terpolymers consisting of difluoroethylene, tetrafluoroethylene and chlorotrifluoroethylene (or hexafluoropropylene) were prepared and tested for tensile strenth, adhesive strength to acrylic resin, water sorption, contact angle, shore hardness, and toxicity by hemolysis test, cell culture test and extraction test. One of the selected terpolymer showed less water sorption (0.1 mg/cm2), stronger tensile strength (160 kg/cm2) and adhesive strength (110 kg/cm2) than the silicone rubber lining material. The toxicity test results suggested that the terpolymer will pose a low potential acute toxicity in vivo. All the test results seem to suggest that the polyfluoroethylene elastomer described here is a promising soft liner material for denture base.

摘要

硅橡胶传统上用作义齿基托的衬里软质材料。然而,它仍有一些性能需要改进,例如与丙烯酸树脂的粘结强度差、变色、降解以及念珠菌滋生。为此,我们尝试应用化学稳定性好的聚氟乙烯共聚物。制备了由二氟乙烯、四氟乙烯和氯三氟乙烯(或六氟丙烯)组成的三元共聚物,并对其拉伸强度、与丙烯酸树脂的粘结强度、吸水率、接触角、邵氏硬度以及通过溶血试验、细胞培养试验和萃取试验进行的毒性进行了测试。所选的一种三元共聚物显示出比硅橡胶衬里材料更低的吸水率(0.1mg/cm²)、更高的拉伸强度(160kg/cm²)和粘结强度(110kg/cm²)。毒性试验结果表明该三元共聚物在体内的潜在急性毒性较低。所有试验结果似乎都表明,这里描述的聚氟乙烯弹性体是一种很有前景的义齿基托软衬材料。

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