合成奥西洛托毒素 D 及其类似物的路线。
Synthetic Route to Oscillatoxin D and Its Analogues.
机构信息
Graduate School of Bioagricultural Sciences, Nagoya University , Chikusa, Nagoya 464-8601, Japan.
出版信息
Org Lett. 2017 Nov 3;19(21):5992-5995. doi: 10.1021/acs.orglett.7b03032.
PMID:29072467
Abstract
O-Methyloscillatoxin D and its analogues were concisely synthesized by a bioinspired intramolecular Mukaiyama aldol reaction as a key step, which involves the construction of a novel spiro-ether moiety.
摘要
O-甲基麦角新碱 D 及其类似物通过生物启发的分子内 Mukaiyama 缩合反应作为关键步骤进行了简洁合成，该反应涉及新型螺醚部分的构建。
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