用于在水中微波辐射下高效实现芳基卤化物铃木偶联反应的新型吡啶基钯（II）配合物。
Novel pyridine-based Pd(II)-complex for efficient Suzuki coupling of aryl halides under microwaves irradiation in water.
作者信息
Althagafi Ismail I, Shaaban Mohamed R, Al-Dawood Aisha Y, Farag Ahmad M
机构信息
Department of Chemistry, Faculty of Applied Science, Umm Al-Qura University, Makkah Almukaramah, Mecca, Saudi Arabia.
Department of Chemistry, Faculty of Science, Cairo University, Giza, 12613, Egypt.
出版信息
Chem Cent J. 2017 Sep 18;11(1):88. doi: 10.1186/s13065-017-0320-2.
Abstract
Suzuki C-C cross-coupling of aryl halides with aryl boronic acids using new phosphene-free palladium complexes as precatalysts was investigated. A pyridine-based Pd(II)-complex was used in open air under thermal as well as microwave irradiation conditions using water as an eco-friendly green solvent.
摘要
研究了使用新型无膦钯配合物作为预催化剂，芳基卤化物与芳基硼酸的铃木碳-碳交叉偶联反应。在热辐射和微波辐射条件下，于空气中使用基于吡啶的钯（II）配合物，并以水作为环保型绿色溶剂。
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