铑（III）催化的酚和苯胺的直接邻位杂化。
Rh(III)-Catalyzed Direct ortho-Chalcogenation of Phenols and Anilines.
机构信息
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University , 29 Wangjiang Road, Chengdu 610064, PR China.
出版信息
J Org Chem. 2017 Dec 1;82(23):12430-12438. doi: 10.1021/acs.joc.7b02221. Epub 2017 Nov 14.
PMID:29094940
Abstract
A highly efficient Rh(III)-catalyzed direct C-H chalcogenation of phenols and anilines has been achieved with the assistance of the 2-pyridyl group. The reaction features a broad substrate scope, good functional group tolerance, complete monothiolation selectivity, and easily removable directing group.
摘要
在 2-吡啶基的辅助下，实现了高效的 Rh(III)-催化酚类和苯胺的直接 C-H 硫代化反应。该反应具有广泛的底物范围、良好的官能团耐受性、完全的单硫代选择性和易于去除的导向基团。
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