Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, c/Catedrático José Beltrán, 2, 46980 Paterna, Spain.
Chem Soc Rev. 2018 Jan 22;47(2):533-557. doi: 10.1039/c7cs00653e.
In this review, we show the different approaches developed so far to prepare metal-organic frameworks (MOFs) presenting electronic functionalities, with particular attention to magnetic properties. We will cover the chemical design of frameworks necessary for the incorporation of different magnetic phenomena, as well as the encapsulation of functional species in their pores leading to hybrid multifunctional MOFs combining an extended lattice with a molecular lattice.
在这篇综述中,我们展示了迄今为止为制备具有电子功能的金属有机骨架(MOFs)而开发的不同方法,特别关注其磁性。我们将涵盖为了纳入不同磁性现象而对框架进行的化学设计,以及将功能物种封装在其孔中以制备具有扩展晶格和分子晶格的混合多功能 MOFs。