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贵金属纳米团簇的荧光增强。

Fluorescence enhancement for noble metal nanoclusters.

机构信息

Department of Basic Science, Jinzhou Medical University, Jinzhou 121001, PR China.

Department of Basic Science, Jinzhou Medical University, Jinzhou 121001, PR China.

出版信息

Adv Colloid Interface Sci. 2017 Dec;250:25-39. doi: 10.1016/j.cis.2017.11.001. Epub 2017 Nov 7.

Abstract

Noble metal nanoclusters have attracted great attentions in the area of fluorescence related applications due to their special properties such as low toxicity, excellent photostability and bio-compatibility. However, they still describe disadvantages for low quantum yield compared to quantum dots and organic dyes though the brightness of the fluorescence play an important role for the efficiency of the applications. Attentions have been attracted for exploring strategies to enhance the fluorescence based on the optical fundamentals through various protocols. Some methods have already been successfully proposed for obtaining relative highly fluorescent nanoclusters, which will potentially describe advantages for the application. In this review, we summarize the approach for enhancement of the fluorescence of the nanoclusters based on the modification of the properties, improvement of the synthesis process and optimization of the environment. The limitation and directions for future development of the fabrication of highly fluorescent metal nanoclusters are demonstrated.

摘要

贵金属纳米团簇由于其低毒性、优异的光稳定性和生物相容性等特殊性质,在荧光相关应用领域引起了极大的关注。然而,与量子点和有机染料相比,它们的量子产率仍然较低,尽管荧光的亮度对应用的效率起着重要的作用。人们已经注意到通过各种方案从光学基础出发探索提高荧光的策略。已经提出了一些获得相对高荧光纳米团簇的方法,这将为应用提供潜在的优势。在这篇综述中,我们总结了基于修饰性质、改进合成工艺和优化环境来增强纳米团簇荧光的方法。展示了高荧光金属纳米团簇制造的局限性和未来发展方向。

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