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基于力学增强的超长 MnO 纳米线复合结构的可编辑超级电容器,具有可定制的拉伸性。

Editable Supercapacitors with Customizable Stretchability Based on Mechanically Strengthened Ultralong MnO Nanowire Composite.

机构信息

Innovative Centre for Flexible Devices (iFLEX), School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798, Singapore.

Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Singapore, 138634, Singapore.

出版信息

Adv Mater. 2018 Jan;30(2). doi: 10.1002/adma.201704531. Epub 2017 Nov 14.

Abstract

Although some progress has been made on stretchable supercapacitors, traditional stretchable supercapacitors fabricated by predesigning structured electrodes for device assembling still lack the device-level editability and programmability. To adapt to wearable electronics with arbitrary configurations, it is highly desirable to develop editable supercapacitors that can be directly transferred into desirable shapes and stretchability. In this work, editable supercapacitors for customizable shapes and stretchability using electrodes based on mechanically strengthened ultralong MnO nanowire composites are developed. A supercapacitor edited with honeycomb-like structure shows a specific capacitance of 227.2 mF cm and can be stretched up to 500% without degradation of electrochemical performance, which is superior to most of the state-of-the-art stretchable supercapacitors. In addition, it maintains nearly 98% of the initial capacitance after 10 000 stretch-and-release cycles under 400% tensile strain. As a representative of concept for system integration, the editable supercapacitors are integrated with a strain sensor, and the system exhibits a stable sensing performance even under arm swing. Being highly stretchable, easily programmable, as well as connectable in series and parallel, an editable supercapacitor with customizable stretchability is promising to produce stylish energy storage devices to power various portable, stretchable, and wearable devices.

摘要

尽管在可拉伸超级电容器方面已经取得了一些进展,但通过预先设计结构化电极来进行器件组装的传统可拉伸超级电容器仍然缺乏器件级的可编辑性和可编程性。为了适应具有任意结构的可穿戴电子设备,非常需要开发可编辑的超级电容器,这些超级电容器可以直接转换为所需的形状和可拉伸性。在这项工作中,使用基于机械强化的超长 MnO 纳米线复合材料的电极开发了用于可定制形状和可拉伸性的可编辑超级电容器。具有蜂窝状结构的超级电容器具有 227.2 mF cm 的比电容,并且可以拉伸至 500%而不会降低电化学性能,这优于大多数最先进的可拉伸超级电容器。此外,它在 400%拉伸应变下经过 10 000 次拉伸和释放循环后,仍保持初始电容的近 98%。作为系统集成概念的代表,可编辑超级电容器与应变传感器集成在一起,即使在手臂摆动下,该系统也表现出稳定的传感性能。可编辑超级电容器具有高可拉伸性、易于编程性以及串联和并联的连接性,有望生产出时尚的储能设备,为各种便携式、可拉伸和可穿戴设备提供动力。

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