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伏安法用于环境中重金属离子鉴定与检测的综述。

A review of the identification and detection of heavy metal ions in the environment by voltammetry.

作者信息

Lu Yuanyuan, Liang Xinqiang, Niyungeko Christophe, Zhou Junjie, Xu Jianming, Tian Guangming

机构信息

College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058, China.

College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058, China.

出版信息

Talanta. 2018 Feb 1;178:324-338. doi: 10.1016/j.talanta.2017.08.033. Epub 2017 Aug 24.

Abstract

Currently, environmental pollution by heavy metals is a global problem. Therefore, it is crucial to develop effective detection techniques to determine the levels of heavy metal contamination in various mediums. Voltammetry is a highly sensitive electrochemical method used for the in situ detection of heavy metal ions. This study investigates the current trends related to electrode modification, developments in materials, and optimization of the experimental parameters. We discuss the sensing performance of four kinds of nanomaterials capable of inorganic modification (metal nanoparticles, metal oxides, carbonaceous nanomaterials, and their nanocomposites). The impact of several important factors, such as the deposition potential and time, buffer solution types, and pH on the sensitivity, reproducibility, stability, and anti-interference ability of the detection process, especially with regard to the co-detection of several heavy metal ions, was reviewed. We noted that in addition to the application of voltammetry to water-related issues, it is suitable for rapid and simple identification and analyses of heavy metals in polluted soil and other mediums. Thus, it is important to conduct additional research on the application of voltammetry to this area.

摘要

目前,重金属造成的环境污染是一个全球性问题。因此,开发有效的检测技术以确定各种介质中的重金属污染水平至关重要。伏安法是一种用于原位检测重金属离子的高灵敏度电化学方法。本研究调查了与电极修饰、材料发展以及实验参数优化相关的当前趋势。我们讨论了四种能够进行无机修饰的纳米材料(金属纳米颗粒、金属氧化物、碳质纳米材料及其纳米复合材料)的传感性能。综述了沉积电位和时间、缓冲溶液类型以及pH值等几个重要因素对检测过程的灵敏度、重现性、稳定性和抗干扰能力的影响,特别是对于几种重金属离子的同时检测。我们注意到,除了将伏安法应用于与水相关的问题外,它还适用于对污染土壤和其他介质中的重金属进行快速简单的识别和分析。因此,对伏安法在该领域的应用进行更多研究很重要。

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