Feng Jiajing, Jiang Wei, Wang Zhaohui
CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China.
University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
Chem Asian J. 2018 Jan 4;13(1):20-30. doi: 10.1002/asia.201701424. Epub 2017 Dec 7.
Rylene imide dyes have been among the most promising organic semiconducting materials for several years due to their remarkable optoelectronic properties and high chemical/thermal stability. In the past decades, various excellent rylene imide dyes have been developed for optoelectronic devices, such as organic solar cells (OSCs) and organic field-effect transistors (OFETs). Recently, tremendous progress of perylene diimides (PDIs) and their analogues for use in OSCs has been achieved, which can be attributed to their ease of functionalization. In this review, we will mainly focus on the synthetic strategies toward to latest PDI dyes and higher rylene imide analogues. A variety of compounds synthesized from different building blocks are summarized, and some properties and applications are discussed.
由于具有卓越的光电性能和高化学/热稳定性，苝酰亚胺染料多年来一直是最具前景的有机半导体材料之一。在过去几十年中，已开发出各种用于光电器件的优异苝酰亚胺染料，如有机太阳能电池（OSCs）和有机场效应晶体管（OFETs）。最近，用于有机太阳能电池的苝二酰亚胺（PDIs）及其类似物取得了巨大进展，这可归因于它们易于功能化。在本综述中，我们将主要关注最新的苝二酰亚胺染料和更高的苝酰亚胺类似物的合成策略。总结了由不同结构单元合成的各种化合物，并讨论了一些性质和应用。
